Van Damme and mullet take care of business in this scene from Timecop.
Top 5 Deaths by Instantly Freezing and Breaking Apart (no, Terminator 2 doesn't count)
5) Airborne - 1998 movie, not the 1993 skating movie. Guy get blasted with some liquid nitrogen, his legs snap, and he breaks into pieces
4) Timecop - When one of the henchmen gets blasted with LN2, Van Damme kicks and shatters his arm to pieces and he falls off a ledge to his death
3.) Mindhunters - Christian Slater's death is pretty similar to the scene in Airborne when you think about it